In my experience doing a bit more than 10% can be helpful in the event of underextrusion, plus I’ve seen it add a bit more rigidity. But you’re right that there are diminishing returns till you start maxing out the infill.
4 perimeters at 0.6mm or 6 at 0.4 should be fine.
Cute cat! Nevermore and Bentobox are two super popular ones.
Since you’re running an E3 V2, first make sure you’ve replaced the hotend with an all-metal design. The stock hotend has the PTFE tube routed all the way into the hotend, which is fine for low temp materials like PLA, but can result in off-gassing at higher temperatures such as those used by ASA and some variants of PETG. The PTFE particles are almost certainly not good to breathe in during the long term, and can even be deadly to certain animals such as birds at small quantities.